Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Des catalyseurs prometteurs pour transformer les microplastiques en carburant utilisable
Les microplastiques, omniprésents et dangereux pour l’environnement, constituent un défi majeur. Dr. Manish Shetty de l’Université Texas A&M travaille à leur décomposition avant qu’ils ne pénètrent dans les écosystèmes. Son approche utilise des solvants faiblement dosés agissant comme sources d’hydrogène pour décomposer les polymères de condensation, tels que le PET, en composés aromatiques réutilisables comme le p-xylène, un précurseur pour carburants et produits chimiques.
En exploitant des catalyseurs capables de transférer et d’utiliser l’hydrogène libéré par des porteurs organiques, cette méthode offre une solution innovante pour la gestion des déchets et la durabilité dans l’industrie chimique. Shetty souligne que ce procédé pourrait contribuer à l’abandon progressif des combustibles fossiles, notamment en intégrant l’hydrogène vert produit par électrolyse de l’eau, ouvrant la voie à des applications de valorisation des déchets en milieu urbain.
https://phys.org/news/2024-11-catalysts-potential-microplastics-usable-fuel.html
Polyéthylène fonctionnalisé : de nouvelles propriétés antibactériennes pour des applications durables
Le polyéthylène (PE), reconnu pour sa polyvalence et sa durabilité, reste limité par sa faible réactivité chimique. Pour repousser ces limites, l’incorporation de groupes fonctionnels polaires, tels que les amines, représente une avancée prometteuse. Grâce au procédé de l’hydroaminoalkylation, des chercheurs ont réussi à aminer le PE de manière efficace et à transformer ces amines en groupes ammonium antibactériens.
Sous l’impulsion de Saeed Ataie et de son équipe à l’Université de la Colombie-Britannique, ce procédé catalytique permet de modifier le PE en une seule étape, évitant la dégradation du polymère et travaillant sous conditions douces. L’ajout de groupes amines a montré une amélioration des propriétés physiques et chimiques du PE, notamment une cristallisation plus rapide et une meilleure hydrophilie.
La conversion des groupes amines en groupes ammonium, grâce à un traitement acide, confère au PE des propriétés antibactériennes puissantes, détruisant efficacement les membranes cellulaires des bactéries. Testé contre Staphylococcus aureus, ce PE modifié a démontré une élimination complète des bactéries en un temps d’exposition court, ouvrant la voie à des applications pratiques comme les revêtements antibactériens.
Une percée catalytique pour le recyclage des polyoléfines : promesse et défis
Des chercheurs de l’université de Berkeley ont mis au point un procédé innovant pour le recyclage des polyéthylènes (PE) et polypropylènes (PP), principaux contributeurs aux déchets plastiques mondiaux. Utilisant une combinaison de catalyseurs solides à base de sodium sur alumine et d’oxyde de tungstène sur silice, ce procédé décompose ces polymères en gaz hydrocarbonés, tels que le propylène et l’isobutylène, réutilisables dans la fabrication de nouveaux plastiques.
Avec un rendement de transformation atteignant 90 % pour des mélanges PE/PP, cette technologie promet une avancée vers une économie circulaire, réduisant la dépendance au pétrole et les émissions de gaz à effet de serre. Toutefois, des défis subsistent : la température de catalyse élevée (600 °C) implique une consommation énergétique importante et un potentiel de formation de dioxines, tandis que le coût de production pourrait être non compétitif face aux plastiques vierges en raison des besoins en tri et en nettoyage des matières premières.
Techniques de l’Ingénieur Remplacer les PFAS : innovations prometteuses en revêtements polymères
Les PFAS, bien que toxiques et persistants dans l’environnement, demeurent irremplaçables en raison de leurs propriétés uniques. Cependant, le Fraunhofer IFAM a développé des solutions de substitution efficaces, notamment dans le domaine médical, où ces substances sont couramment utilisées. En exploitant la chimie des organosilicones, les chercheurs ont mis au point des revêtements biocompatibles et inertes, adaptés aux normes strictes du secteur. Des revêtements tels que ReleasePLAS® et PLASLON® offrent des propriétés de non-adhérence et de libération sans agent, facilitant la production sans compromettre la performance. Ces solutions innovantes seront présentées lors du salon COMPAMED 2024, ouvrant de nouvelles perspectives pour des applications médicales et industrielles durables.
Innovations Report Nouveau procédé pour des thermoplastiques plus performants : cristaux stéréocomplexes
Des chercheurs de la TU Eindhoven, en collaboration avec le BESSY II, ont mis en lumière un procédé innovant améliorant la résilience des mélanges thermoplastiques à base de PLA (acide polylactique) et de PVDF (polyfluorure de vinylidène). L’étude, publiée dans ACS Applied Materials & Interfaces, révèle que l’ajout de copolymères PLA spécifiques (comme SAD) favorise la formation de couches cristallines stéréocomplexes aux interfaces des phases polymères. Ces couches, observées grâce à la spectroscopie infrarouge et à l’imagerie nano-IR sur la ligne IRIS de BESSY II, augmentent la température de cristallisation et améliorent le transfert des contraintes mécaniques, avec une extension à la rupture accrue jusqu’à 250 %. Cette avancée ouvre la voie à la création de polymères à hautes performances compatibles, essentiels pour des applications exigeantes en durabilité et résistance.
Recyclage optimisé du polypropylène : la rhéologie en ligne pour des formulations plus rentables
Les chercheurs de Fraunhofer LBF ont perfectionné les tests rhéologiques en ligne pour mieux stabiliser les recyclats de polypropylène (PP), garantissant ainsi des formulations de plastique de haute qualité à moindre coût. Le processus d’auto-oxydation des polymères, accéléré par les températures élevées du moulage et du compoundage, entraîne une dégradation des chaînes polymériques, rendant le recyclage difficile sans stabilisants adéquats.
Traditionnellement, la détermination du bon dosage d’antioxydants nécessitait des séries de tests coûteuses. L’approche novatrice du Fraunhofer LBF consiste à caractériser le PP fondu en temps réel pendant le compoundage grâce à un rhéomètre en ligne mesurant la viscosité en cisaillement et en extension. Cette méthode permet de corréler directement la concentration en stabilisants à la stabilité du polymère, optimisant ainsi leur quantité ajoutée.
Les premiers essais sur un PP vierge faiblement stabilisé ont montré que l’ajout précis d’antioxydants maintient la viscosité et le poids moléculaire souhaités. Des tests sur des recyclats post-industriels et post-consommateurs ont révélé que les stabilisants sont essentiels pour préserver les propriétés des matériaux, particulièrement pour les lots post-consommateurs où les antioxydants résiduels sont faibles.
Cette avancée aide les développeurs de formulations à ajuster les stabilisants de manière efficace, minimisant les coûts et maximisant la durabilité des plastiques recyclés. En outre, la mesure de la viscosité en extension offre des informations précieuses sur la stabilité de la matière fondue, essentielle pour des applications comme le soufflage de films.
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Etiam feugiat quis risus quis tempus. Morbi pharetra volutpat ligula ut placerat. Morbi sagittis ornare tellus, at molestie urna suscipit id. Praesent non est quis ante pretium ullamcorper. Lorem ipsum dolor sit amet, consectetur adipiscing elit. Vestibulum ante ipsum primis in faucibus orci luctus et ultrices posuere cubilia Curae; Integer sodales nisi justo, a varius nisi viverra accumsan. Quisque eleifend velit sed suscipit convallis. Donec ac facilisis massa. Donec euismod erat molestie nisi condimentum mattis. Nunc eu eros lacinia, vestibulum nibh vitae, varius magna. Aliquam erat volutpat. Suspendisse potenti.
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