Le réseau
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L'organisation
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La structure de veille et de réflexion prospective
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Actualités
Un hydrogel innovant pour préserver les bois immergés des épaves
Des chercheurs ont mis au point un hydrogel révolutionnaire capable de préserver les bois anciens issus d’épaves marines sans nécessiter de longs processus de séchage, souvent destructeurs pour ces objets historiques. Ce gel, présenté dans ACS Sustainable Chemistry & Engineering, neutralise les acides et stabilise les bois immergés tout en se dissolvant progressivement, évitant ainsi les dommages de surface.
Les bois issus des épaves, comme ceux du Nanhai One (un navire vieux de 800 ans), sont fragilisés par des bactéries productrices d’acide et des champignons lignivores. Les méthodes traditionnelles de préservation, telles que le séchage par lyophilisation ou le remplacement de l’eau par des polymères sous pression, sont longues et peuvent altérer la structure des objets.
Le nouvel hydrogel, composé de polymères, de bicarbonate de potassium (neutralisant acide) et de nitrate d’argent (antimicrobien), pénètre dans le bois et agit sur 1 cm de profondeur en 10 jours. Les gels liquéfiables, contenant moins de nitrate d’argent, se dissolvent plus rapidement et préservent mieux la structure cellulaire des bois, réduisant leur fragilité.
Cette technologie offre une solution durable et respectueuse pour conserver les bois historiques issus des épaves, tout en permettant une meilleure compréhension de notre passé maritime.
https://phys.org/news/2024-12-hydrogel-waterlogged-wood-shipwrecks.html
Une avancée révolutionnaire pour le recyclage des plastiques par pyrolyse à grande échelle
L’équipe de recherche dirigée par le Dr Byungwook Hwang de l’Institut coréen de recherche en énergie (KIER) a développé une technologie de pyrolyse novatrice utilisant un lit fluidisé circulant (CFB). Ce procédé permet de recycler les déchets plastiques en huile de pyrolyse de manière continue et à grande échelle, surmontant les limites des méthodes traditionnelles.
La méthode CFB repose sur la circulation de particules catalytiques chauffées entre un réacteur de combustion et un réacteur de pyrolyse, assurant un transfert de chaleur efficace et ininterrompu. Contrairement au procédé au four rotatif, limité à 20 tonnes de déchets par jour, cette technologie est conçue pour une évolutivité industrielle, essentielle pour atteindre l’objectif de la Corée de traiter 900 000 tonnes de déchets plastiques par an d’ici 2030.
Les essais réalisés ont démontré une capacité de traitement jusqu’à 100 kg par jour, avec un rendement en huile de pyrolyse amélioré de 37 % et une qualité notablement supérieure grâce à une teneur accrue en fractions légères (45 %). Cette avancée technologique représente un pas décisif vers une gestion durable des plastiques, répondant aux enjeux environnementaux mondiaux.
https://phys.org/news/2024-12-plastic-circulation-large-scale-pyrolysis.html
Une avancée majeure dans la simulation mécanique atomistique des matériaux
Des chercheurs, menés par Alessio Zaccone, ont résolu un problème fondamental en mécanique des matériaux à l’échelle atomique, permettant de simuler leur déformation mécanique sur des échelles de temps réalistes. Ce défi persistait en raison des limites des méthodes actuelles de dynamique moléculaire (MD), qui sont incapables de représenter des processus dynamiques aux basses fréquences expérimentales.
Leur approche repose sur les déplacements non affins des atomes, des trajectoires perturbées nécessaires pour atteindre l’équilibre mécanique à chaque étape de déformation. En intégrant des modes vibratoires normaux dans leurs calculs, ils ont obtenu une modélisation des matériaux à des fréquences autour du Hertz, soit 10 ordres de grandeur plus basses que les simulations traditionnelles.
Cette méthode a été validée sur un polymère époxy réticulé, reproduisant ses propriétés viscoélastiques avec une précision remarquable et sans ajustement de paramètres. Ces résultats ouvrent la voie à des prédictions atomiques précises et au développement de matériaux innovants aux performances accrues.
https://phys.org/news/2024-12-scientists-hardest-problems-atomic-scale.html
Une avancée dans le recyclage des matériaux composites grâce à la biocatalyse
Face aux défis environnementaux posés par la gestion des matériaux composites en fin de vie, des chercheurs de l’Université de Californie du Sud ont mis au point une méthode innovante combinant recyclage et valorisation des fibres de carbone et de la matrice polymère.
Des matériaux composites aux propriétés uniques, mais difficiles à recycler
Les composites, prisés dans des industries comme l’aéronautique et l’énergie, associent légèreté, résistance et durabilité. Cependant, leur recyclage reste problématique, particulièrement pour les polymères renforcés de fibres de carbone (CFRP), utilisés dans les avions ou les pales d’éoliennes. Actuellement, les techniques existantes détruisent la matrice polymère pour récupérer les fibres, limitant leur efficacité.
Le procédé développé repose sur la conversion de la matrice polymère des CFRP en acide benzoïque, une substance utilisée comme substrat par Aspergillus nidulans, un champignon filamenteux génétiquement modifié. Par biocatalyse, ce dernier transforme l’acide benzoïque en OTA, un composé d’intérêt médical pour la fabrication d’antibiotiques et d’anti-inflammatoires.
L’approche permet également de préserver 97 % des propriétés mécaniques des fibres de carbone, rendant possible leur réutilisation dans de nouveaux composites. Cette double valorisation, combinant recyclage des fibres et transformation des polymères en produits à haute valeur ajoutée, marque une avancée majeure.
Ce procédé, reliant chimie, biotechnologie et durabilité, offre une perspective concrète pour gérer les déchets composites à grande échelle tout en réduisant leur impact environnemental.
Techniques de l’Ingénieur Récupération des microplastiques grâce à des nanoparticules magnétiques
Alors que les microplastiques envahissent l’environnement et infiltrent les organismes vivants, des chercheurs de l’Université de Sao Paulo ont mis au point une méthode innovante pour extraire ces particules de l’eau à l’aide d’aimants.
Le procédé repose sur des nanoparticules magnétiques fonctionnalisées avec de la polydopamine, un polymère dérivé de la dopamine. La polydopamine, connue pour ses propriétés adhésives, se lie fortement aux fragments de micro- et nanoplastiques en PET (polyéthylène téréphtalate), un plastique couramment utilisé dans les bouteilles et textiles. Une fois attachées aux particules de plastique, les nanoparticules magnétiques permettent leur extraction via un simple champ magnétique.
Vers une dégradation enzymatique
En parallèle, l’équipe explore l’utilisation de la lipase, une enzyme capable de décomposer le PET en ses monomères initiaux : l’acide téréphtalique et l’éthylène glycol. Ces composés pourraient ensuite être réutilisés pour synthétiser de nouveaux plastiques.
Cette méthode ouvre des perspectives prometteuses pour lutter contre la pollution plastique, notamment en combinant récupération et recyclage des microplastiques à l’échelle moléculaire.
Techniques de l’Ingénieur Un catalyseur pour transformer le méthane en polymères utiles
Des ingénieurs chimistes du MIT ont conçu un catalyseur hybride capable de convertir le méthane, un gaz à effet de serre puissant, en polymères à température ambiante et à pression atmosphérique. Ce procédé novateur pourrait contribuer à réduire les émissions de méthane tout en valorisant ce gaz sous forme de produits utiles.
Le méthane, majoritairement émis par l’agriculture, les décharges et la gestion du gaz naturel, est environ 25 fois plus puissant que le CO₂ en termes de réchauffement climatique. En utilisant une combinaison de zéolite (un minéral argileux) et d’enzyme naturelle, les chercheurs transforment le méthane en méthanol, puis en formaldéhyde. Ce dernier sert de précurseur à la fabrication de polymères tels que la résine urée-formaldéhyde, largement utilisée dans les panneaux de particules et les textiles.
Un procédé prometteur
Ce catalyseur, utilisant des ressources accessibles comme l’oxygène de l’air, pourrait être appliqué à grande échelle, notamment pour enduire des surfaces exposées au méthane ou sceller des fuites dans les pipelines de gaz naturel.
Avec cette approche, les chercheurs ouvrent la voie à des solutions innovantes pour convertir des gaz à effet de serre en matériaux industriels, tout en s’attaquant aux défis climatiques.
https://www.sciencedaily.com/releases/2024/12/241204114309.htm
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Adhérez au GFP
Devenez un membre et découvrez les avantages d’un abonnement GFP.
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Sections locales GFP
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